Ionic bonding

[!def] metal atoms react with non-metal atoms

  • Metal atoms lose, non-metal atoms gain their outer electrons to form ions
  • The positive and negative ions are held together by strong electrostatic forces of attraction between opposite charges

Ionic bond

[!def] The force of attraction hold ionic compounds together

Examples

$$Na^+ + Cl^- \to NaCl$$
$$Mg^{2+} + O^{2-} \to MgO$$

Lattice structure

  • Ionic compounds have a giant lattice structure (no molecule because it has no units)
  • the atoms are arranged in an ordered and repeating fashion
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Properties

  • They have high melting and boiling points
  • The greater the charge on the ions, the stronger the electrostatic forces and the higher the melting point will be
  • good conductors of electricity in the molten state or in solution
  • poor conductors in the **solid state

Covalent Bonding

[!def] pairs of electrons are shared between atoms

  • Only non-metal elements participate in covalent bonding
  • each atom gains a full outer shell of electrons
  • Covalently bonded substances may consist of small molecules or giant molecules
  • When two or more atoms are covalently bonded together, we describe them as ‘molecules

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Examples

$H_{2}O$
$CH_{4}$
$NH_{2}$
$H_{2} \ O_{2} \ Cl_{2}$ - single bond

Metallic bonding

[!def] the strong force of attraction between the positive metal ions and the delocalised electrons

  • Metals consist of giant structures
  • Within the metal lattice, the atoms lose their outer electrons and become positively charged metal ions
    • The outer electrons no longer belong to any specific metal atom and are said to be delocalised
    • This means they can move freely between the positive metal ions and act like a “sea of electrons”
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Properties

high melting and boiling points 
- strong electrostatic forces of attraction which needs lots of energy to be broken

  • Metals are good conductors of heat and electricity
    • The delocalised electrons are free to move and carry a charge through the whole structure
  • Most metals are malleable(opposite. brittle)
    • This means they can be hammered into shape
    • This is because the atoms are arranged in layers which can slide over each when force is applied
Ionic Simple (Covalent) Giant (Covalent) Metallic
Metals and non-metals Non-metals Non-metals Metals
Loss and gain of electrons by atoms Share pairs of electrons between atoms Share pairs of electrons between atoms Outer electrons free to move
+ and - ions formed attract each other Small groups of atoms held together Billions of atoms are held together Billions of positive metal ions
Ionic lattice structure A molecular structure Giant covalent lattice structure Giant metallic lattice structure
Conduct when melten Don’t conduct Don’t conduct good conductivity
High melting point Low melting point High melting point High melting point